Edited by Pietro VINCENZINI World Academy of Ceramics and's 12th INTERNATIONAL CERAMICS CONGRESS Proceedings of the 12 PDF

By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Maurizio FERRARI CNR-IFN, Italy Mrityunjay SINGH NASA Glenn Research Center, USA

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Extra info for 12th INTERNATIONAL CERAMICS CONGRESS Proceedings of the 12 th International Ceramics Congress, part of CIMTEC 2010- 12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 6-11, 2010 PART J including: Symposium

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The distance between the two electrodes was fixed to 1 mm with a nonconductive spacer. 5 mM dicyclohexylcarbodiimide (DCC) solution. A positive potential was applied to the 2aminoethanethiol-modified gold substrate, while a negative potential was applied to the counter electrode. 10V of potential vas applied to the system for 20 minutes. After the deposition, the system was washed with ethanol and dried with nitrogen stream. 5ml of concentred gold nanoparticles solution were added to 1 ml of 5mM 2-aminoethanethiol solution in ethanol.

Moreover, the Au NPs functionalized with aminic groups can bind charged molecules as for examples anions, allowing a close contact between the gold nanoparticles and the analytes. This is a favorable situation because close contact between gold nanoparticles and the molecules are required for SERS experiments. In these experiments, we tested the possibility to detect sulphate anions from diluted solutions in water. Sulphate, as well as perchlorate, dichromate, are polyatomic anions and exhibit Raman active vibrational modes.

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12th INTERNATIONAL CERAMICS CONGRESS Proceedings of the 12 th International Ceramics Congress, part of CIMTEC 2010- 12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 6-11, 2010 PART J including: Symposium by Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Maurizio FERRARI CNR-IFN, Italy Mrityunjay SINGH NASA Glenn Research Center, USA


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