New PDF release: Advances In Chemical Propulsion, Science To Technology

By Roy,G D Ed

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Fluid Mechanics 308:63–96. 7. Gutmark, E. , K. S. Schadow, and K. H. Yu. 1997. Mixing enhancement in supersonic free shear flows. Annual Reviews Fluid Mechanics 27:375–417. 8. Baer, D. , M. E. Newfield, N. Gopaul, and R. K. Hanson. 1994. Multiplexed diode laser sensor system for simultaneous H2 O, O2 and temperature measurements. Optic Letters 19(22):1900–2. 9. Strykowski, P. , and D. J. Forliti. 2000. Flow control applications using countercurrent shear. In: Recent advances in experimental fluid mechanics.

Of a special interest would be the tungsten ones. While they are not yet available on the market, making and testing a large variety of them in the laboratory is planned. Testing at least one tungsten catalyst, for example one analogous to 23, on at least the three monomers that appear in this study is absolutely necessary before any conclusion can be drawn. 7 CONCLUDING REMARKS Strained polycyclic hydrocarbons in the form of (1) 1,4-disubstituted cubyl systems with highly unsaturated side-chains, (2) 1,2-disubstituted cubanes, (3) cubylazido derivatives, and (4) high-energy polymers have been synthesized in small quantities sufficient for lab-scale studies of their physical and chemical properties.

2 Synthesis of Polyunsaturated Cubanes Next, the attention was turned to addition of azido groups to carbon–carbon double bonds of side-chains attached to the cubyl ring system. 3 Synthesis of compound 5 In the case of 1,4-disubstituted system, tetraazide 6 was formed proceeding from 5 as shown in Fig. 2. Compound 5 in Fig. 2 was synthesized as shown in Fig. 3. Compound 5 was protected as the bis-TBDMS ether (5 −→ 2). Treatment with NaN3 /(PhIO)n yielded 10 as a mixture of diastereomers (Fig. 4).

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Advances In Chemical Propulsion, Science To Technology by Roy,G D Ed


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