Download e-book for iPad: Aquatic Redox Chemistry by Paul G. Tratnyek, Timothy J. Grundl, and Stefan B. Haderlein

By Paul G. Tratnyek, Timothy J. Grundl, and Stefan B. Haderlein (Eds.)

ISBN-10: 0841226520

ISBN-13: 9780841226524

ISBN-10: 0841226539

ISBN-13: 9780841226531

content material: PREFACE ; 1. advent TO AQUATIC REDOX CHEMISTRY ; TIMOTHY J. GRUNDL, STEFAN HADERLEIN, JAMES T. NURMI, AND PAUL G. TRATNYEK ; 2. THERMODYNAMIC REDOX CALCULATIONS FOR ONE AND ELECTRON move STEPS: IMPLICATIONS FOR HALIDE OXIDATION AND HALOGEN ENVIRONMENTAL biking ; GEORGE W. LUTHER, III ; three. ONE-ELECTRON relief POTENTIALS FROM CHEMICAL constitution idea CALCULATIONS ; ERIC J. BYLASKA, ALEXANDRA J. SALTER-BLANC, AND PAUL G. TRATNYEK ; four. THERMODYNAMIC keep watch over ON TERMINAL ELECTRON move AND METHANOGENESIS ; CHRISTIAN BLODAU ; five. REDOX CHEMISTRY AND average natural subject (NOM): GEOCHEMISTS' DREAM, ANALYTICAL CHEMISTS>' NIGHTMARE ; DONALD L. MACALADY AND KATHERINE WALTON-DAY ; 6. ELECTRON SHUTTLING through traditional natural subject: 20 years AFTER ; GARRISON SPOSITO ; 7. ELECTROCHEMISTRY OF average natural topic ; JAMES T. NURMI AND PAUL G. TRATNYEK ; eight. PATHWAYS CONTRIBUTING TO THE FORMATION and rot OF FERROUS IRON IN SUNLIT average WATERS ; SHIKHA GARG, ANDREW L. ROSE, AND T. DAVID WAITE ; nine. THE function OF IRON COORDINATION within the construction OF REACTIVE OXIDANTS FROM FERROUS IRON OXIDATION through OXYGEN AND HYDROGEN PEROXIDE ; CHRISTINA KEENAN REMUCAL AND DAVID L. SEDLAK ; 10. TIO2 PHOTOCATALYSIS FOR THE REDOX CONVERSION OF AQUATIC toxins ; JAESANG LEE, JUNGWON KIM, AND WONYONG CHOI ; eleven. CHLORINE dependent OXIDANTS FOR WATER PURIFICATION AND DISINFECTION ; GREGORY V. KORSHIN ; 12. REMEDIATION OF CHEMICALLY-CONTAMINATED WATERS utilizing SULFATE RADICAL REACTIONS: KINETIC reviews ; STEPHEN P. MEZYK, KIMBERLY A. RICKMAN, GARRETT MCKAY, CHARLOTTE M. HIRSCH, XUEXIANG HE, AND DIONYSIOS D. DIONYSIOU ; thirteen. VOLTAMMETRY OF SULFIDE NANOPARTICLES AND THE FES(AQ) challenge ; G. R. HELZ, I. CIGLENECKI, D. KRZNARIC, AND E. BURA-NAKIC ; 14. REDOX REACTIVITY OF ORGANICALLY COMPLEXED IRON(II) SPECIES WITH AQUATIC CONTAMINANTS TIMOTHY J. STRATHMANN ; 15. FE2+ SORPTION on the FE OXIDE-WATER INTERFACE: A REVISED CONCEPTUAL FRAMEWORK ; CHRISTOPHER A. GORSKI AND MICHELLE M. SCHERER ; sixteen. REDOX pushed strong ISOTOPE FRACTIONATION ; JAY R. BLACK, JEFFREY A. CRAWFORD, SETH JOHN, AND ABBY KAVNER ; 17. REDOX houses OF STRUCTURAL FE IN SMECTITE CLAY MINERALS ; ANKE NEUMANN, MICHAEL SANDER, AND THOMAS B. HOFSTETTER ; 18. REACTIVITY OF ZEROVALENT METALS IN AQUATIC MEDIA: results OF natural floor COATINGS ; PAUL G. TRATNYEK, ALEXANDRA J. SALTER-BLANC, JAMES T. NURMI, JAMES E. AMONETTE, JUAN LIU, CHONGMIN WANG, ALICE DOHNALKOVA, AND DONALD R. BAER ; 19. present views at the MECHANISMS OF CHLOROHYDROCARBON DEGRADATION IN SUBSURFACE ENVIRONMENTS: perception FROM KINETICS, PRODUCT FORMATION, PROBE MOLECULES, AND ISOTOPE FRACTIONATION ; MARTIN ELSNER AND THOMAS B. HOFSTETTER ; 20. DEGRADATION ROUTES OF RDX IN a number of REDOX platforms ; ANNAMARIA HALASZ AND JALAL HAWARI ; 21. function OF COUPLED REDOX variations within the MOBILIZATION AND SEQUESTRATION OF ARSENIC ; JANET G. HERING, STEPHAN J. HUG, CLAIRE FARNSWORTH, AND PEGGY A. O>'DAY ; 22. REDOX methods AFFECTING THE SPECIATION OF TECHNETIUM, URANIUM, NEPTUNIUM, AND PLUTONIUM IN AQUATIC AND TERRESTRIAL ENVIRONMENTS ; EDWARD J. O'LOUGHLIN, MAXIM I. BOYANOV, DIONYSIOS A. ANTONOPOULOS, AND KENNETH M. KEMNER ; 23. price CONTROLLING methods within the TRANSFORMATION OF TETRACHLOROETHYLENE AND CARBON TETRACHLORIDE less than IRON decreasing AND SULFATE decreasing stipulations ; ELIZABETH C. BUTLER, YIRAN DONG, LEE R. KRUMHOLZ, XIAOMING LIANG, HONGBO SHAO, AND YAO TAN ; 24. using CHEMICAL PROBES FOR THE CHARACTERIZATION OF THE principal ABIOTIC REDUCTANTS IN ANAEROBIC SEDIMENTS ; HUICHUN (JUDY) ZHANG, DALIZZA COLON, JOHN F. KENNEKE, AND ERIC J. WEBER ; 25. THE position OF shipping IN AQUATIC REDOX CHEMISTRY ; WOLFGANG KURTZ AND STEFAN PEIFFER ; 26. EVOLUTION OF REDOX strategies IN GROUNDWATER ; PETER B. MCMAHON, FRANCIS H. CHAPELLE, AND PAUL M. BRADLEY ; EDITORS' BIOGRAPHIES ; INDEXES ; writer INDEX ; topic INDEX

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D) reaction O4 coupled with reactions CL2, Br2, Io2. Oxidation of Halides to X· and X2 by Fe(III) and Mn(III,IV) Solid Phases – Sedimentary Reactions Other common environmental oxidants, especially in sediments, are the (oxy)hydroxides of Fe(III) and Mn(III,IV). Figure 6 shows that the one electron oxidation of halides to halide radicals (X·) for chloride (figure 6a) and bromide (figure 6b) are not favorable. Iodide oxidation (figure 6c) is only favorable for MnOOH and Mn3O4 at pH ≤ 2. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2011.

We have used Hoffstetter’s dataset to encompass all of this early work, and summarized it in Table 2. Recently, Phillips et al. (74) compiled a set of purely measured values to validate their theoretical calculations (which are discussed below). Phillips et al. drew from the Schwarzenbach et al. dataset, and added additional data from Riefler and Smets (75) and others (76–78).

Luther, G. , III; Greenwood, J. E. The kinetics of iodine disproportionation: a system of parallel second-order reactions sustained by a multi-species pre-equilibrium. Phys. Chem. Chem. Phys. 2003, 5, 3428–3435. Brookins, D. G. Eh-pH diagrams for Geochemistry. Springer-Verlag: Berlin, 1988; p176. Luther, G. , III; Cole, H. Iodine speciation in Chesapeake Bay waters. Mar. Chem. 1988, 24, 315–325. Luther, G. ; Cullen, J. Redox chemistry of iodine in seawater: frontier molecular orbital theory considerations.

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Aquatic Redox Chemistry by Paul G. Tratnyek, Timothy J. Grundl, and Stefan B. Haderlein (Eds.)


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