By F Albert Cotton; et al
Content material: Metal-metal a number of bonds in dinuclear clusters / F.A. Cotton, R.A. Walton -- advancements in transition steel cluster chemistry / G. Schmid -- Spectroscopic houses of the quasi one-dimensional tetracyanoplatinate (II) compounds / G. Gilemann, H. Yersin
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This molecule has now been studied spectroscopically by the supersonic jet technique 126). The new results are more detailed and more precise than, but not essentially different from, those previously available and cited in MBBMA. The ground state is confirmed to be 1Zg+ (meaning that all electrons are paired in fully occupied Metal-Metal Multiple Bonds in Dinuclear Clusters 27 molecular orbitals). An electronic transition from this ground state to a 1Zu+ state was found to occur without any appreciable weakening of the bond.
87, 715 (1983) 134. Walch, S. , Bauschlicker, C. , Roos, B. , Nelin, C. : Chem. Phys. Letters 103, 175 (1983) 135. , Freeman, A. , Ellis, D. : Phys. Rev. Letters 50, 488 (1983) 136. Langridge-Smith, P. R. , Morse, M. , Hansen, G. , Smalley, R. , Merer, A. : J. Chem. Phys. 80, 595 (1984) 137. Cotton, F. : J. Am. Chem. Soc. 104, 7025 (1982) 138. Cotton, F. " Nouv. J. Chem. 8, 331 (1984) 139. Atha, P. , Hillier, I. , Guest, M. : Mol. Phys. 46, 437 (1982) 140. Atha, P.
Tocher, D. , Walkinshaw, M. S. Dalton Trans. 1983, 2109 118. Chakravarty, A. , Cotton, F. , Tocher, D. S. Chem. Commun. 1984, 501; Inorg. Chem. 23, 4697 (1984) 119. Chakravarty, A. , Cotton, F. , Tocher, D. , Tocher, J. : Organometallics 4, 8 (1985) 120. Chakravarty, A. , Cotton, F. , Tocher, D. : Inorg. Chem. 24, 1334 (1985) 121. Chakravarty, A. , Cotton, F. , Tocher, D. : ibid. 23, 4693 (1984) 122. Tetrick, S. , Coombe, V. , Heath, G. , Stephenson, T. , Walton, R. : ibid. 23, 4657 (1984) 123.
Clusters by F Albert Cotton; et al