New PDF release: Comprehensive Coordination Chemistry II. Transition Metal

By J. A. McCleverty, T.J. Meyer

ISBN-10: 0080437486

ISBN-13: 9780080437484

ISBN-10: 0080443281

ISBN-13: 9780080443287

Entire Coordination Chemistry II (CCC II) is the sequel to what has develop into a vintage within the box, entire Coordination Chemistry, released in 1987. CCC II builds at the first and surveys new advancements authoritatively in over two hundred newly comissioned chapters, with an emphasis on present tendencies in biology, fabrics technological know-how and different parts of latest medical curiosity.

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Extra resources for Comprehensive Coordination Chemistry II. Transition Metal Groups 9 - 11

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The introduction of a second bridging bis-tridentate oligopyridine completes the six-coordinate geometry of the two CoII centers. 260 This complex was characterized intact by ESMS, with the anion apparently trapped in the central cavity, a concept supported by the crystal structure of the perchlorate analog (Figure 5). 262 26 Cobalt 1 1a N1s N1 Co1 N2 2a 2 3 N3a N3 4a N4a N4 N5a 4 3a 6a 5a N5 N2s Co2 N7e 6 N6 7a N7 7 Figure 4 Mononuclear quinquepyridine (40 ,4000 -bis(4-chlorophenyl analogue) CoII complex (left, reproduced with permission of the Royal Society of Chemistry from J.

416 These form via a photochemically induced labile solvent complex, or else through thermally induced substitution into carbonyl compounds. (v) Ethers (m) Acyclic. Ether oxygens are not considered strong donors for cobalt. 417 Ethers are met as a component donor group in mixeddonor polydentates; an example is the N,O,N-donor bis(pyrazolylethyl)ether,418 which binds meridionally to CoII. 389 Reacted alone, the tetrahedral Co(bbp)2Cl2 forms with the ligand a P-bound monodentate; however, when Ag(O3SCF3) was included, the octahedral trans(P),trans(O),trans(O)-Co(bbp)2(O3SCF3)2 forms where the ligand is P,O-chelated and in addition the weak ligand triflate is also bound.

266 The meso-substituted complex porphyrin Co(TPyP) (42) complex bears four active pyridyl donors which readily react with four equivalents of [Ru(NH3)5(OH2)]2þ to produce the tetra-ruthenated derivative. The four Ru centers are sufficiently remote that their RuIII/II potentials coincide. Under steady state conditions [Co(TPyP)]{Ru(NH3)5}4]8þ (43) adsorbed onto a pyrolytic graphite working electrode catalyzes the reduction of dioxygen (Figure 6). 268 The roles of the Ru and Co centers in catalysis were elucidated by varying the number of Ru centers and their ancillary ligands.

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Comprehensive Coordination Chemistry II. Transition Metal Groups 9 - 11 by J. A. McCleverty, T.J. Meyer


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